postgresql -- an ORDBMS
As I learn more, I'll post more things that I should remember. ;) 
 
- Show list of current connections:
ps auxww | grep post[g]res:  
Monitoring from the shell seems to work best. The format is "postgres: user database host activity"
-- from http://www.postgresql.org/docs/8.1/interactive/monitoring.html
select * from pg_catalog.pg_stat_activity; 
currently failing my tests.
More info on the pg_stat interface at: 
http://www.postgresql.org/docs/8.1/interactive/monitoring-stats.html
 - List tables and indices by disk space used:
SELECT relname, relpages FROM pg_class ORDER BY relpages DESC;
from http://www.postgresql.org/docs/8.1/interactive/diskusage.html
 - Variable substitution:
 \set var 3
 select * from test where test_column = :var
from http://www.postgresql.org/docs/8.1/interactive/app-psql.html
 - Row-level locking for updates:
select * from :table where :testcondition for update;
from http://www.postgresql.org/docs/8.1/interactive/explicit-locking.html
 - Temporary tables:
create temporary table foo AS select * from bar;
from http://www.postgresql.org/docs/8.1/static/sql-createtableas.html
 - Create if not exist:
if not exists ( select 1 from pg_class where relname = 'table_X' ) then 
create table tableX ...;
end if; 
from http://www.varlena.com/GeneralBits/64.php
 - What functions have been defined?:
select * from pg_proc, pg_language
 
where pg_proc.prolang = pg_language.oid and pg_language.lanname = 'plpgsql';
from http://archives.postgresql.org/pgsql-de-allgemein/2004-09/msg00001.php
 
Is there some project in particular that you are going to use postgres for? - Nathan
I've used it for personal data for a while. I'm now ramping up usage for collecting some web-available data on my colo.